Every Daemon is a splinter of its divine master, a distorted reflection of mortal yearning, a shard of emotion and dark desire given form and licence to destroy. Thus does every Daemon reflect something of its master's presence and personality.
Source: Warhammer: The Old World Online Rules Index
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Many models in this army list have the Daemons of Khorne, Daemons of Nurgle, Daemons of Slaanesh or Daemons of Tzeentch special rule listed among their special rules. These special rules represent the Daemonic Alignment of that model, indicating to which of theRuinous Powers the Daemon is bound:
A model cannot have more than one Daemonic Alignment.
All models within a unit must have the same Daemonic Alignment.
A character with a Daemonic Alignment can only join a unit with the same Daemonic Alignment, or with no Daemonic Alignment.
A character with no Daemonic Alignment can join any unit as normal.